by Staff Writers
Livermore CA (SPX) Feb 28, 2017
Lawrence Livermore scientists have collaborated with an interdisciplinary team of researchers including colleagues from Sandia National Laboratories to develop an efficient hydrogen storage system that could be a boon for hydrogen powered vehicles.
Hydrogen is an excellent energy carrier, but the development of lightweight solid-state materials for compact, low-pressure storage is a huge challenge.
Complex metal hydrides are a promising class of hydrogen storage materials, but their viability is usually limited by slow hydrogen uptake and release. Nanoconfinement - infiltrating the metal hydride within a matrix of another material such as carbon - can, in certain instances, help make this process faster by shortening diffusion pathways for hydrogen or by changing the thermodynamic stability of the material.
However, the Livermore-Sandia team, in conjunction with collaborators from Mahidol University in Thailand and the National Institute of Standards and Technology, showed that nanoconfinement can have another, potentially more important consequence. They found that the presence of internal "nano-interfaces" within nanoconfined hydrides can alter which phases appear when the material is cycled.
The researchers examined the high-capacity lithium nitride (Li3N) hydrogen storage system under nanoconfinement. Using a combination of theoretical and experimental techniques, they showed that the pathways for the uptake and release of hydrogen were fundamentally changed by the presence of nano-interfaces, leading to dramatically faster performance and reversibility. The research appears on the cover of the Feb. 23 edition of the journal Advanced Materials Interfaces.
"The key is to get rid of the undesirable intermediate phases, which slow down the material's performance as they are formed or consumed. If you can do that, then the storage capacity kinetics dramatically improve and the thermodynamic requirements to achieve full recharge become far more reasonable," said Brandon Wood, an LLNL materials scientist and lead author of the paper.
"In this material, the nano-interfaces do just that, as long as the nanoconfined particles are small enough. It's really a new paradigm for hydrogen storage, since it means that the reactions can be changed by engineering internal microstructures."
The Livermore researchers used a thermodynamic modeling method that goes beyond conventional descriptions to consider the contributions from the evolving solid phase boundaries as the material is hydrogenated and dehydrogenated. They showed that accounting for these contributions eliminates intermediates in nanoconfined lithium nitride, which was confirmed spectroscopically.
Beyond demonstrating nanoconfined lithium nitride as a rechargeable, high-performing hydrogen-storage material, the work establishes that proper consideration of solid-solid nanointerfaces and particle microstructure are necessary for understanding hydrogen-induced phase transitions in complex metal hydrides.
"There is a direct analogy between hydrogen storage reactions and solid-state reactions in battery electrode materials," said Tae Wook Heo, another LLNL co-author on the study.
"People have been thinking about the role of interfaces in batteries for some time, and our work suggests that some of the same strategies being pursued in the battery community could also be applied to hydrogen storage. Tailoring morphology and internal microstructure could be the best way forward for engineering materials that could meet performance targets."
Zurich, Switzerland (SPX) Feb 14, 2017
Global climate change is affecting our planet and mankind; climate science is thus instrumental in informing policy makers about its dangers, and in suggesting emission limits. Science also shows that staying within limits, while meeting the aspirations of a growing global population requires fundamental changes in energy conversion and storage. The majority of low-carbon technology innova ... read more
Lawrence Livermore National Laboratory
Powering The World in the 21st Century at Energy-Daily.com
|The content herein, unless otherwise known to be public domain, are Copyright 1995-2017 - Space Media Network. All websites are published in Australia and are solely subject to Australian law and governed by Fair Use principals for news reporting and research purposes. AFP, UPI and IANS news wire stories are copyright Agence France-Presse, United Press International and Indo-Asia News Service. ESA news reports are copyright European Space Agency. All NASA sourced material is public domain. Additional copyrights may apply in whole or part to other bona fide parties. Advertising does not imply endorsement, agreement or approval of any opinions, statements or information provided by Space Media Network on any Web page published or hosted by Space Media Network. Privacy Statement|