by Staff Writers
Washington DC (SPX) Jan 04, 2017
Germanium may not be a household name like silicon, its group-mate on the periodic table, but it has great potential for use in next-generation electronics and energy technology.
Of particular interest are forms of germanium that can be synthesized in the lab under extreme pressure conditions. However, one of the most-promising forms of germanium for practical applications, called ST12, has only been created in tiny sample sizes - too small to definitively confirm its properties.
"Attempts to experimentally or theoretically pin down ST12-germanium's characteristics produced extremely varied results, especially in terms of its electrical conductivity," said Carnegie's Zhisheng Zhao, the first author on a new paper about this form of germanium.
The study's research team, led by Carnegie's Timothy Strobel, was able to create ST12-germanium in a large enough sample size to confirm its characteristics and useful properties. Their work is published by Nature Communications.
"This work will be of interest to a broad range of readers in the field of materials science, physics, chemistry, and engineering," explained Carnegie's Haidong Zhang, the co-leading author.
ST12-germanium has a tetragonal structure - the nameST12 means "simple tetragonal with 12 atoms."(See illustration below.) It was created by putting germanium under about 138 times normal atmospheric pressure (14 gigapascals) and then decompressing it slowly at room temperature.
The millimeter-sized samples of ST12-germanium that the team created were large enough that they could be studied using a variety of spectroscopic techniques in order to confirm its long-debated characteristics.
Like the most common, diamond-cubic form of germanium, they found that ST12 is a semiconductor with a so-called indirect band gap. Metallic substances conduct electrical current easily, whereas insulating materials conduct no current at all. Semiconducting materials exhibit mid-range electrical conductivity.
When semiconducting materials are subjected to an input of a specific energy, bound electrons can be moved to higher-energy, conducting states. The specific energy required to make this jump to the conducting state is defined as the "band gap." While direct band gap materials can effectively absorb and emit light, indirect band gap materials cannot.
"Our team was able to quantify ST12's optical band gap - where visible light energy can be absorbed by the material - as well as its electrical and thermal properties, which will help define its potential for practical applications," Strobel said.
"Our findings indicate that due to the size of its band gap, ST12-germanium may be a better material for infrared detection and imaging technology than the diamond-cubic form of the element already being used for these purposes."
Carnegie Institution for Science
Computer Chip Architecture, Technology and Manufacture
Nano Technology News From SpaceMart.com
|The content herein, unless otherwise known to be public domain, are Copyright 1995-2017 - Space Media Network. All websites are published in Australia and are solely subject to Australian law and governed by Fair Use principals for news reporting and research purposes. AFP, UPI and IANS news wire stories are copyright Agence France-Presse, United Press International and Indo-Asia News Service. ESA news reports are copyright European Space Agency. All NASA sourced material is public domain. Additional copyrights may apply in whole or part to other bona fide parties. All articles labeled "by Staff Writers" include reports supplied to Space Media Network by industry news wires, PR agencies, corporate press officers and the like. Such articles are individually curated and edited by Space Media Network staff on the basis of the report's information value to our industry and professional readership. Advertising does not imply endorsement, agreement or approval of any opinions, statements or information provided by Space Media Network on any Web page published or hosted by Space Media Network. Privacy Statement|