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Soluble elements from a new corner of the periodic table by Staff Writers Wurzburg, Germany (SPX) Jun 09, 2016
It is one of the more memorable experiments of high school chemistry lessons: when elemental sodium comes into contact with water it burns and explodes. Sodium simply isn't happy in its elemental form, making it highly reactive. This is more or less true for all of the other elements from the so-called "s-block" of the periodic table, to which sodium belongs. A chemistry research group at the Julius-Maximilians-Universitat (JMU) of Wurzburg in Bavaria, Germany, has now, for the first time, tamed one of these "wild" s-block metals. The researchers constructed molecules that incorporate one atom of the alkaline earth metal beryllium in its elemental state. That the molecules do not immediately decompose at room temperature is thanks to stabilization by two cyclic ligands. The breakthrough from the research team of Professor Holger Braunschweig is presented in the top-tier journal Nature Chemistry, thanks to the unexpectedly high stability of the molecules. These results from the JMU chemistry laboratories are expected to open a new era for the chemistry of the elements of this corner of the periodic table.
Promising candidates for challenging reactions For reasons of sustainability and cost, replacing these expensive catalysts with alternatives from the main group elements of the periodic table - many of which are abundant in the Earth's crust - would be a huge step forward. This often means accessing the elemental states of these atoms in molecular systems. However, this is by no means trivial, as many of the potential candidate atoms - sodium being an extreme example - are highly reactive in their elemental states. Recent success has been made with p-block elements such as silicon, tin and boron, while this new work is the first ever example with an s-block metal, beryllium.
Developing alternatives to toxic beryllium Given their success in incorporating elementary beryllium into a stable molecule, the chances are good that this could also work with other s-block metals. "Our discovery is a first step in capturing other s-block metal atoms in their elemental state, which we hope will promote reactions that usually only proceed with expensive heavy metals," says Ph.D. student Julia Schuster, who synthesised the new molecules. The research group is currently developing similar methods for other s-block metals.
Related Links University of Wurzburg Space Technology News - Applications and Research
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