by Staff Writers
Boston MA (SPX) Apr 04, 2017
From an electron's point of view, graphene must be a hair-raising thrill ride. For years, scientists have observed that electrons can blitz through graphene at velocities approaching the speed of light, far faster than they can travel through silicon and other semiconducting materials. Graphene, therefore, has been touted as a promising successor to silicon, with the potential to enable faster, more efficient electronic and photonic devices.
But manufacturing pristine graphene - a single, perfectly flat, ultrathin sheet of carbon atoms, precisely aligned and linked together like chickenwire - is extremely difficult. Conventional fabrication processes often generate wrinkles, which can derail an electron's bullet-train journey, significantly limiting graphene's electrical performance.
Now engineers at MIT have found a way to make graphene with fewer wrinkles, and to iron out the wrinkles that do appear. After fabricating and then flattening out the graphene, the researchers tested its electrical conductivity. They found each wafer exhibited uniform performance, meaning that electrons flowed freely across each wafer, at similar speeds, even across previously wrinkled regions.
In a paper published in the Proceedings of the National Academy of Sciences, the researchers report that their techniques successfully produce wafer-scale, "single-domain" graphene - single layers of graphene that are uniform in both atomic arrangement and electronic performance.
"For graphene to play as a main semiconductor material for industry, it has to be single-domain, so that if you make millions of devices on it, the performance of the devices is the same in any location," says Jeehwan Kim, the Class of 1947 Career Development Assistant Professor in the departments of Mechanical Engineering and Materials Science and Engineering at MIT. "Now we can really produce single-domain graphene at wafer scale."
Kim's co-authors include Sanghoon Bae, Samuel Cruz, and Yunjo Kim from MIT, along with researchers from IBM, the University of California at Los Angeles, and Kyungpook National University in South Korea.
A patchwork of wrinkles
The CVD process can produce relatively large, macroscropic wrinkles in graphene, due to the roughness of the underlying copper itself and the process of pulling the graphene out from the acid. The alignment of carbon atoms is not uniform across the graphene, creating a "polycrystalline" state in which graphene resembles an uneven, patchwork terrain, preventing electrons from flowing at uniform rates.
In 2013, while working at IBM, Kim and his colleagues developed a method to fabricate wafers of single-crystalline graphene, in which the orientation of carbon atoms is exactly the same throughout a wafer.
Rather than using CVD, his team produced single-crystalline graphene from a silicon carbide wafer with an atomically smooth surface, albeit with tiny, step-like wrinkles on the order of several nanometers. They then used a thin sheet of nickel to peel off the topmost graphene from the silicon carbide wafer, in a process called layer-resolved graphene transfer.
Kim says this ironing method would not work on CVD-fabricated graphene, as the wrinkles generated through CVD are much larger, on the order of several microns.
"The CVD process creates wrinkles that are too high to be ironed out," Kim notes. "For silicon carbide graphene, the wrinkles are just a few nanometers high, short enough to be flattened out."
To test whether the flattened, single-crystalline graphene wafers were single-domain, the researchers fabricated tiny transistors on multiple sites on each wafer, including across previously wrinkled regions.
"We measured electron mobility throughout the wafers, and their performance was comparable," Kim says. "What's more, this mobility in ironed graphene is two times faster. So now we really have single-domain graphene, and its electrical quality is much higher [than graphene-attached silicon carbide]."
Kim says that while there are still challenges to adapting graphene for use in electronics, the group's results give researchers a blueprint for how to reliably manufacture pristine, single-domain, wrinkle-free graphene at wafer scale.
"If you want to make any electronic device using graphene, you need to work with single-domain graphene," Kim says. "There's still a long way to go to make an operational transistor out of graphene. But we can now show the community guidelines for how you can make single-crystalline, single-domain graphene."
Rochester NY (SPX) Mar 31, 2017
A new class of carbon nanotubes could be the next-generation clean-up crew for toxic sludge and contaminated water, say researchers at Rochester Institute of Technology. Enhanced single-walled carbon nanotubes offer a more effective and sustainable approach to water treatment and remediation than the standard industry materials - silicon gels and activated carbon - according to a paper pub ... read more
Massachusetts Institute of Technology
Carbon Worlds - where graphite, diamond, amorphous, fullerenes meet
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