by Staff Writers
Munich, Germany (SPX) Oct 19, 2017
Power on the go is in demand: The higher the battery capacity, the larger the range of electric cars and the longer the operating time of cell phones and laptops. Dr. Jennifer Ludwig of the Technical University of Munich (TUM) has developed a process that allows a fast, simple, and cost-effective production of the promising cathode material lithium cobalt phosphate in high quality. The chemist was awarded the Evonik Research Prize for her work.
Hope is pink: The powder that Jennifer Ludwig carefully pours into a glass bowl and which glows pink in the light of the laboratory lamp has the potential to significantly improve the performance of future batteries. "Lithium cobalt phosphate can store substantially more energy than conventional cathode materials," explains the chemist.
Working in the group of Tom Nilges, head of the Professorship of Synthesis and Characterization of Innovative Materials, the chemist has developed a process for producing the pink powder quickly, with minimal amounts of energy and in the highest quality.
Battery researchers have been considering lithium cobalt phosphate a material of the future for some time. It operates at higher voltages than the traditionally employed lithium iron phosphate and thus, attains a higher energy density - 800 watt hours per kilogram instead of just under 600 watt hours.
Previous process: expensive and energy-intensive
Furthermore, the resulting crystals exhibit sufficient ionic conductivity in only one direction. Over most of the surface, the chemical reaction between the electrode material and the electrolyte in the batteries progresses very slowly.
The reactants are placed in a Teflon container together with a solvent and are then heated. A mere 600 W are sufficient to achieve the 250 C required to stimulate the crystal formation.
The flat platelets created in the process measure less than one micrometer across and are only a few hundred nanometers thick, with the axis of maximum conductivity oriented towards the surface. "This shape ensures better electrochemical performance because the lithium ions need to move only short distances within the crystals," explains Ludwig.
Steering the reaction
Jennifer Ludwig succeeded in elucidating the reaction mechanism, isolating the compound and determining its structure and properties. Since the new compound is unsuitable as a battery material, she modified the reaction so that only the desired lithium cobalt phosphate is produced.
"With this new production process, we can now create high-performance, platelet-shaped lithium cobalt phosphate crystals with tailored properties in high quality," says Professor Nilges. "Thus, a further hurdle on the path to new high-voltage materials has been taken."
Raleigh NC (SPX) Oct 18, 2017
New research from North Carolina State University, MIT and the University of Michigan finds that the surface texture of microparticles in a liquid suspension can cause internal friction that significantly alters the suspension's viscosity - effectively making the liquid thicker or thinner. The finding can help address problems for companies in fields from biopharmaceuticals to chemical manufactu ... read more
Technical University of Munich
Space Technology News - Applications and Research
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