Free Newsletters - Space News - Defense Alert - Environment Report - Energy Monitor
by Staff Writers
Eindhoven, Netherlands (SPX) Jul 09, 2013
Researchers of MESA+, the research institute for nanotechnology of the University of Twente, in cooperation with researchers of the University of Strasbourg and Eindhoven University of Technology, are the first to successfully create perfect one-dimensional molecular wires of which the electrical conductivity can almost entirely be suppressed by a weak magnetic field at room temperature.
The underlying mechanism is possibly closely related to the biological compass used by some migratory birds to find their bearings in the geomagnetic field. This spectacular discovery may lead to radically new magnetic field sensors, for smartphones for example. The leading scientific journal Science publishes the research results on 4 July.
In their experiments, the researchers made use of DXP, the organic molecule which is a red dye of the same type as once used by Ferrari for their famous Testarossa. In order to thread the molecules so that they form one-dimensional chains of 30 to 100 nanometers in length - 1 nanometer being 1 billionth of a meter - they applied a smart trick: they locked the molecules in zeolite crystals.
Zeolites are porous minerals composed of silicon, aluminum and oxygen atoms with narrow channels, like the lift shafts in a block of flats. The diameter of the channels in the zeolites is only 1 nanometer, just a little wider than the molecule's diameter. This enabled the researchers to create chains of aligned molecules inside the zeolite channel, which are only 1 molecule wide.
Molecular electric wires
"But the behavior of these wires is simply spectacular when applying a magnetic field," he adds. This is because electrical conductivity nearly completely breaks down in a magnetic field of just a few milliteslas in size, a field which you could easily generate with a refrigerator magnet. Van der Wiel: "The fact that the effect is so dramatic and occurs even in small magnetic fields at room temperature makes this result very special."
However, the ultra-high magnetoresistance which has been measured in Twente was achieved without any magnetic materials. The researchers ascribe this effect to the interaction between the electrons carrying electricity and the magnetic field which is generated by the surrounding atomic nuclei in the organic molecules.
Current suppression in a small magnetic field can ultimately be traced back to the famous Pauli exclusion principle, the quantum mechanical principle that states that no two electrons (fermions) may have identical quantum numbers. Since the electric wires are essentially one-dimensional, the effect of the Pauli exclusion principle is dramatic, comparable to an accident on a single-lane road that brings traffic to a standstill. This interpretation is supported by calculations.
Article 'Ultra-High Magnetoresistance at Room Temperature in Molecular Wires' Science
Eindhoven University of Technology
Space Technology News - Applications and Research
|The content herein, unless otherwise known to be public domain, are Copyright 1995-2014 - Space Media Network. AFP, UPI and IANS news wire stories are copyright Agence France-Presse, United Press International and Indo-Asia News Service. ESA Portal Reports are copyright European Space Agency. All NASA sourced material is public domain. Additional copyrights may apply in whole or part to other bona fide parties. Advertising does not imply endorsement,agreement or approval of any opinions, statements or information provided by Space Media Network on any Web page published or hosted by Space Media Network. Privacy Statement|