. | . |
First direct look at how light excites electrons to kick off a chemical reaction by Staff Writers Stanford CA (SPX) May 04, 2020
The first step in many light-driven chemical reactions, like the ones that power photosynthesis and human vision, is a shift in the arrangement of a molecule's electrons as they absorb the light's energy. This subtle rearrangement paves the way for everything that follows and determines how the reaction proceeds. Now scientists have seen this first step directly for the first time, observing how the molecule's electron cloud balloons out before any of the atomic nuclei in the molecule respond. While this response has been predicted theoretically and detected indirectly, this is the first time it's been directly imaged with X-rays in a process known as molecular movie-making, whose ultimate goal is to observe how both electrons and nuclei act in real time when chemical bonds form or break. Researchers from Brown University, the University of Edinburgh and the Department of Energy's SLAC National Accelerator Laboratory reported their findings in Nature Communications. "In past molecular movies, we have been able to see how atomic nuclei move during a chemical reaction," said Peter Weber, a chemistry professor at Brown and senior author of the report. "But the chemical bonding itself, which is a result of the redistribution of electrons, was invisible. Now the door is open to watching the chemical bonds change during reactions."
A model for important biological reactions In studies going back almost 20 years, scientists have studied how CHD's ring breaks apart when light hits it - first with electron diffraction techniques, and more recently with SLAC's "electron camera," MeV-UED, and X-ray free-electron laser, the Linac Coherent Light Source (LCLS). These and other studies around the world have revealed how the reaction proceeds in finer and finer detail. Four years ago, researchers from Brown, SLAC and Edinburgh used LCLS to make a molecular movie of the CHD ring flying apart, - the first-ever molecular movie recorded using X-rays. This achievement was listed as one of the 75 most important scientific breakthroughs to emerge from a DOE national laboratory, alongside discoveries such as the decoding of DNA and the detection of neutrinos. But none of those previous experiments were able to observe the initial electron-shuffling step, because there was no way to tease it apart from the much larger movements of the molecule's atomic nuclei.
Electrons in the spotlight "X-ray scattering has been used to determine the structure of matter for more than 100 years," said Adam Kirrander, a senior lecturer at Edinburgh and senior co-author of the study, "but this is the first time the electronic structure of an excited state has been directly observed." The technique used, called non-resonant X-ray scattering, measures the arrangement of electrons in a sample, and the team hoped to capture changes in the distribution of electrons as the molecule absorbed the light. Their measurement bore out that expectation: While the signal from the electrons was weak, the researchers were able to unambiguously capture how the electron cloud deformed into a larger, more diffuse cloud corresponding to an excited electronic state. It was critical to observe these electronic changes before the nuclei started moving. "In a chemical reaction, the atomic nuclei move and it's difficult to disentangle that signal from the other parts that belong to chemical bonds forming or breaking," said Haiwang Yong, a PhD student at Brown University and lead author of the report. "In this study, the change in the positions of atomic nuclei is comparatively small on that timescale, so we were able to see the motions of electrons right after the molecule absorbs light." SLAC senior staff scientist Michael Minitti added, "We're imaging these electrons as they move and shift around. This paves the way to watching electron motions in and around bond breaking and bond formation directly and in real time; in that sense it's similar to photography."
A new kind of physics Melbourne, Australia (The Conversation) Apr 28, 2020 Stephen Wolfram is a cult figure in programming and mathematics. He is the brains behind Wolfram Alpha, a website that tries to answer questions by using algorithms to sift through a massive database of information. He is also responsible for Mathematica, a computer system used by scientists the world over. Last week, Wolfram launched a new venture: the Wolfram Physics Project, an ambitious attempt to develop a new physics of our universe. The new physics, he declares, is computational. The guidin ... read more
|
|
The content herein, unless otherwise known to be public domain, are Copyright 1995-2024 - Space Media Network. All websites are published in Australia and are solely subject to Australian law and governed by Fair Use principals for news reporting and research purposes. AFP, UPI and IANS news wire stories are copyright Agence France-Presse, United Press International and Indo-Asia News Service. ESA news reports are copyright European Space Agency. All NASA sourced material is public domain. Additional copyrights may apply in whole or part to other bona fide parties. All articles labeled "by Staff Writers" include reports supplied to Space Media Network by industry news wires, PR agencies, corporate press officers and the like. Such articles are individually curated and edited by Space Media Network staff on the basis of the report's information value to our industry and professional readership. Advertising does not imply endorsement, agreement or approval of any opinions, statements or information provided by Space Media Network on any Web page published or hosted by Space Media Network. General Data Protection Regulation (GDPR) Statement Our advertisers use various cookies and the like to deliver the best ad banner available at one time. All network advertising suppliers have GDPR policies (Legitimate Interest) that conform with EU regulations for data collection. By using our websites you consent to cookie based advertising. If you do not agree with this then you must stop using the websites from May 25, 2018. Privacy Statement. Additional information can be found here at About Us. |