. | . |
Where did those electrons go? X-ray measurements solve decades-old mystery by Staff Writers Ithaca NY (SPX) Nov 08, 2017
The concept of "valence" - the ability of a particular atom to combine with other atoms by exchanging electrons - is one of the cornerstones of modern chemistry and solid-state physics. Valence controls crucial properties of molecules and materials, including their bonding, crystal structure, and electronic and magnetic properties. Four decades ago, a class of materials called "mixed valence" compounds was discovered. Many of these compounds contain elements near the bottom of the periodic table, so-called "rare-earth" elements, whose valence was discovered to vary with changes in temperature in some cases. Materials comprising these elements can display unusual properties, such as exotic superconductivity and unusual magnetism. But there's been an unsolved mystery associated with mixed valence compounds: When the valence state of an element in these compounds changes with increased temperature, the number of electrons associated with that element decreases, as well. But just where do those electrons go? Using a combination of state-of-the-art tools, including X-ray measurements at the Cornell High Energy Synchrotron Source (CHESS), a group led by Kyle Shen, professor of physics, and Darrell Schlom, the Herbert Fisk Johnson Professor of Industrial Chemistry in the Department of Materials Science and Engineering, have come up with the answer. Their work is detailed in a paper, "Lifshitz transition from valence fluctuations in YbAl3," published in Nature Communications. The lead author is Shouvik Chatterjee, formerly of Shen's research group and now a postdoctoral researcher at the University of California, Santa Barbara. To address this mystery, Chatterjee synthesized thin films of the mixed-valence compound of ytterbium - whose valence changes with temperature - and aluminum, using a process called molecular beam epitaxy, a specialty of the Schlom lab. The group then employed angle-resolved photoemission spectroscopy (ARPES) to investigate the distribution of electrons as a function of temperature to track where the missing electrons went. "Typically for any material, you change the temperature and you measure the number of electrons in a given orbital, and it always stays the same," Shen said. "But people found that in some of these materials, like the particular compound we studied, that number changed, but those missing electrons have to go somewhere." It turns out that when the compound is heated, the electrons lost from the ytterbium atom form their own "cloud," of sorts, outside of the atom. When the compound is cooled, the electrons return to the ytterbium atoms. "You can think of it as two glasses that contain some water," Shen said, "and you're pouring back and forth from one to the other, but the total amount of water in both glasses remains fixed." This phenomenon was first proposed by 20th-century Russian physicist Evgeny Lifshitz, but an answer to the electron mystery hadn't been proposed until now. "These findings point toward the importance of valence changes in these material systems. By changing the arrangement of mobile electrons, they can dramatically influence novel physical properties that can emerge," said Chatterjee. "This places our understanding of these materials on a better footing," Shen said. Other contributors included Ken Finkelstein, senior staff scientist at CHESS; and doctoral students Jacob Ruf and Haofei Wei of the Shen Group.
Tomsk, Russia (SPX) Nov 03, 2017 Dmitry Karlovets, senior researcher at the TSU Faculty of Physics, with Valery Serbo from the Institute of Mathematics of the SB RAS, has shown that it is possible to observe the wave properties of massive particles at room temperature, in practically any modern physics laboratory, because it is only necessary to focus the beam of particles well. The results of the theoretical research were publ ... read more Related Links Cornell University Understanding Time and Space
|
|
The content herein, unless otherwise known to be public domain, are Copyright 1995-2024 - Space Media Network. All websites are published in Australia and are solely subject to Australian law and governed by Fair Use principals for news reporting and research purposes. AFP, UPI and IANS news wire stories are copyright Agence France-Presse, United Press International and Indo-Asia News Service. ESA news reports are copyright European Space Agency. All NASA sourced material is public domain. Additional copyrights may apply in whole or part to other bona fide parties. All articles labeled "by Staff Writers" include reports supplied to Space Media Network by industry news wires, PR agencies, corporate press officers and the like. Such articles are individually curated and edited by Space Media Network staff on the basis of the report's information value to our industry and professional readership. Advertising does not imply endorsement, agreement or approval of any opinions, statements or information provided by Space Media Network on any Web page published or hosted by Space Media Network. General Data Protection Regulation (GDPR) Statement Our advertisers use various cookies and the like to deliver the best ad banner available at one time. All network advertising suppliers have GDPR policies (Legitimate Interest) that conform with EU regulations for data collection. By using our websites you consent to cookie based advertising. If you do not agree with this then you must stop using the websites from May 25, 2018. Privacy Statement. Additional information can be found here at About Us. |