by Staff Writers
Stanford CA (SPX) Jun 20, 2014
Scientists at the Department of Energy's SLAC National Accelerator Laboratory have made the first structural observations of liquid water at temperatures down to minus 51 degrees Fahrenheit, within an elusive "no-man's land" where water's strange properties are super-amplified.
The research, made possible by SLAC's Linac Coherent Light Source (LCLS) X-ray laser and reported June 18 in Nature, opens a new window for exploring liquid water in these exotic conditions, and promises to improve our understanding of its unique properties at the more natural temperatures and states that are relevant to global ocean currents, climate and biology.
Scientists have known for some time that water can remain liquid at extremely cold temperatures, but they've never before been able to examine its molecular structure in this zone.
"Water is not only essential for life as we know it, but it also has very strange properties compared to most other liquids," said Anders Nilsson, deputy director of the SUNCAT Center for Interface Science and Catalysis, a joint SLAC/Stanford institute, and leader of the research. "Now, thanks to LCLS, we have finally been able to enter this cold zone that should provide new information about the unique nature of water."
Not Your Typical Liquid
These traits are amplified when purified water is supercooled. When water is very pure, with nothing to seed the formation of ice crystals, it can remain liquid at much lower temperatures than normal.
The temperature range of water from about minus 42 to minus 172 degrees has been dubbed no-man's land. For decades scientists have sought to better explore what happens to water molecules at temperatures below minus 42 degrees, but they had to rely largely on theory and modeling.
Femtosecond Shutter Speeds
The research showed that water's molecular structure transforms continuously as it enters this realm, and with further cooling the structural changes accelerate more dramatically than theoretical models had predicted.
For this experiment, researchers produced a steady flow of tiny water droplets in a vacuum chamber. As the drops traveled toward the laser beam, some of their liquid rapidly evaporated, supercooling the remaining liquid. (The same process cools us when we sweat.) By adjusting the distance the droplets traveled, the researchers were able to fine-tune the temperatures they reached on arrival at the X-ray laser beam.
"Our dream is to follow these dynamics as far as we can," Nilsson said. "Eventually our understanding of what's happening here in no-man's land will help us fundamentally understand water in all conditions."
DOE/SLAC National Accelerator Laboratory
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