by Staff Writers
Houston TX (SPX) Oct 04, 2016
Rice University scientists working to develop a deeper understanding of the world's most widely used man-made material, concrete, have detailed previously unexplored aspects that affect the energy required to make it and the greenhouse gases released.
The Rice laboratory of materials scientist Rouzbeh Shahsavari developed techniques to not only analyze but also see dislocations in dicalcium silicates (aka belite), a component of Portland cement, and detailed how each of five distinct types contributes to concrete's ease of manufacture and ultimate strength.
The lab's report appears this month in Cement and Concrete Research.
"Though belite is crystalline in nature, the crystals are so small and the material so amorphous that nobody has looked at them with the kind of analytical eye they deserve," Shahsavari said. But fine-tuning them for use in the cement that holds concrete together can help save energy, which in turn leads to a reduction in carbon emissions, he said.
"Putting an atomistic lens on the role of defects on the mechanics and water reactivity of belite crystals can provide new insights on how to modulate the grinding energy of cement clinkers and strength development of concrete," he said. "Both of these factors can significantly contribute to energy saving and reduced environmental footprints due to the use and manufacture of concrete."
Calcium silicates are a key ingredient in industrial clinkers, which are ground and mixed with water to make cement. Compared with tricalcium silicate, the more dominant ingredient in cement, belite can be produced at a much lower temperature.
This temperature is at least 100 degrees Celsius (212 degrees Fahrenheit) lower and makes belite an economical trade; however, it is harder to grind and reacts more slowly with water, which leads to delayed strength development in cement paste. Shahsavari said these issues have curbed the widespread use of belite-based cement in concrete, but his lab has adopted an approach that could bring change.
Belite crystals of calcium, silicon and oxygen mainly take one of two different forms, either monoclinic or orthorhombic, each of which behaves differently at the atomic level. Rice researchers subdivided those into five distinct polymorphic crystals. Through computer simulations and high-resolution electron microscopy, they determined one of the monoclinic forms, dubbed beta-C2S, is the most brittle and possibly the best-suited for cements requiring low-energy manufacture.
Shahsavari said the research provides new insight about the bottom-up engineering of materials that have the properties of cement.
"The physical understanding gained by our high-resolution electron microscopy images, the first of their kind for cement, combined with our atomistic-level computations, can put cement-based materials on equal footing with metallic systems and semiconductors in the emerging application of 'defect-engineering' to boost performance in manufacturability and functionality," he said. "We expect this will lead to energy savings and environmental benefits."
Co-authors of the paper are Rice alumna Lu Chen, now a structural engineer at Arup, and graduate student Lei Tao. The National Science Foundation supported the research. Supercomputers utilized in the research included the NSF-supported DAVinCI supercomputer, administered by Rice's Center for Research Computing and procured in a partnership with Rice's Ken Kennedy Institute for Information Technology, and resources supported by the National Institutes of Health, IBM, Cisco, Qlogic and Adaptive Computing.
Space Technology News - Applications and Research
|The content herein, unless otherwise known to be public domain, are Copyright 1995-2017 - Space Media Network. All websites are published in Australia and are solely subject to Australian law and governed by Fair Use principals for news reporting and research purposes. AFP, UPI and IANS news wire stories are copyright Agence France-Presse, United Press International and Indo-Asia News Service. ESA news reports are copyright European Space Agency. All NASA sourced material is public domain. Additional copyrights may apply in whole or part to other bona fide parties. All articles labeled "by Staff Writers" include reports supplied to Space Media Network by industry news wires, PR agencies, corporate press officers and the like. Such articles are individually curated and edited by Space Media Network staff on the basis of the report's information value to our industry and professional readership. Advertising does not imply endorsement, agreement or approval of any opinions, statements or information provided by Space Media Network on any Web page published or hosted by Space Media Network. Privacy Statement|