. 24/7 Space News .
Fuel Cells: The Next Generation

Illustration only. Credit: Siemens.
Pasadena CA (SPX) Oct 25, 2004
For several years now the Department of Energy (DOE) has been urging the fuel cell community to solve a major problem in the design of solid oxide fuel cells (SOFCs): heat. Such fuel cells could someday provide reliable power for homes and industry, dramatically cutting greenhouse gas emissions as well as other pollutants.

But SOFCs run hot, at temperatures as high as 1000 degrees Celsius (about 1800 degrees Fahrenheit). They're efficient at such temperatures, but only a few costly materials can withstand the heat. Using such materials makes things expensive, and is the reason for the push for lower temperatures by the DOE.

Sossina Haile, an associate professor of materials science and chemical engineering at the California Institute of Technology, is an expert in fuel cells, and she has been whittling away at the heat problem for years.

Now she and her colleagues have not only solved the problem, they've smashed it. They've brought the temperature down to about 600 degrees Celsius (1100 degrees Fahrenheit), while achieving more power output than others are achieving at the higher temperatures - about 1 watt per square centimeter of fuel cell area.

They accomplished this by changing the chemical composition of one component of a fuel cell called the cathode. The cathode is where air is fed in to the fuel cell, and it's where the oxygen is electrochemically reduced to oxygen ions.

The oxygen ions then migrate across the electrolyte (which conducts electricity), to react with fuel at the anode, another fuel cell component. The electrochemical reduction of oxygen is an essential step in the fuel cell's process of generating power.

But the problem with running solid oxide fuel cells at 500 to 700 degrees Celsius is that the cathode becomes inactive when the temperature is less than about 800 degrees Celsius.

Haile and postdoctoral scholar Zongping Shao's insight was to switch out the conventional cathode and replace it with a compound that has a long chemical formula guaranteed to strike fear into the heart of every undergraduate: Ba0.5Sr0.5Co0.8Fe0.2O3-d, but is abbreviated as "BSCF" for short.

What BSCF can do that standard cathodes can't is to allow the oxygen to diffuse through it very rapidly. "In conventional cathodes, the oxygen diffuses slowly, so that even if the electrochemical reaction is fast, the oxygen ions are slow in getting to the electrolyte," says Haile.

"In BSCF the electrochemical reaction is fast and the oxygen ion transport is fast. You have the best combination of properties." This combination is what gives the very high power outputs from Haile's fuel cells.

The work was reported in a recent issue of the journal Nature. Because they are using relatively conventional anodes and electrolytes with this new cathode, says Haile, it would be easy to switch out cathodes in existing fuel cells. That will probably be their next step, says Haile: to partner with a company to produce the next generation of solid-oxide fuel cells.

Related Links
SpaceDaily
Search SpaceDaily
Subscribe To SpaceDaily Express

Sandia Refurbishes It's Fusion Z Machine
Albuquerque NM (SPX) Oct 22, 2004
Sandia National Laboratories' Z machine, which last year emitted neutrons to enter the race to provide the world virtually unlimited electricity from, essentially, seawater, has received approval from the National Nuclear Security Administration (NNSA) to proceed with a $61.7 million refurbishment. The project is called ZR, for Z-Refurbishment.



Thanks for being here;
We need your help. The SpaceDaily news network continues to grow but revenues have never been harder to maintain.

With the rise of Ad Blockers, and Facebook - our traditional revenue sources via quality network advertising continues to decline. And unlike so many other news sites, we don't have a paywall - with those annoying usernames and passwords.

Our news coverage takes time and effort to publish 365 days a year.

If you find our news sites informative and useful then please consider becoming a regular supporter or for now make a one off contribution.
SpaceDaily Contributor
$5 Billed Once


credit card or paypal
SpaceDaily Monthly Supporter
$5 Billed Monthly


paypal only














The content herein, unless otherwise known to be public domain, are Copyright 1995-2016 - Space Media Network. All websites are published in Australia and are solely subject to Australian law and governed by Fair Use principals for news reporting and research purposes. AFP, UPI and IANS news wire stories are copyright Agence France-Presse, United Press International and Indo-Asia News Service. ESA news reports are copyright European Space Agency. All NASA sourced material is public domain. Additional copyrights may apply in whole or part to other bona fide parties. Advertising does not imply endorsement, agreement or approval of any opinions, statements or information provided by Space Media Network on any Web page published or hosted by Space Media Network. Privacy Statement All images and articles appearing on Space Media Network have been edited or digitally altered in some way. Any requests to remove copyright material will be acted upon in a timely and appropriate manner. Any attempt to extort money from Space Media Network will be ignored and reported to Australian Law Enforcement Agencies as a potential case of financial fraud involving the use of a telephonic carriage device or postal service.